In this case an acid medium makes it easier to remove scales off metal. For several decades, chemical mechanical polishing cmp has been the most widely used planarization method in integrated circuits manufacturing. Mechanics, mechanisms and modeling of the chemical. Ep1190006b1 slurry composition and method of chemical. It was first used in the early 1990s for beol metallization to replanarize the wafer.
A cupric salt cmp slurry was employed to improve the throughput and surface finish on a conventional polishing machine. The kemcol 15 machine is ideal for chemical mechanical polishing cmp, and cerium oxide based polishing applications. Dielectric chemical mechanical polishing cmp was implemented in semiconductor fabrication as a. Part of theamerican studies commons this dissertation is brought to you for free and open access by the graduate school at scholar commons. Chemical mechanical planarization of electronic materials by fnu atiquzzaman a thesis submitted in partial fulfillment of the requirements for the degree of master of science department of mechanical engineering college of engineering university of south florida comajor professor. Abrasive for chemical mechanical polishing intechopen. Wo2024971a2 cmp slurry composition for tungsten polishing. Effect of slurry composition on the chemical mechanical polishing of thin diamond films. Precipitation of oxalates from homogenous solution. A discussion started in 2002 but continuing through 2019.
Chemical mechanical polishing includes traditional polishing, eg. Science and technology of advanced materials 2017, 18 1, 654663. Silica base slurry utilization on tungsten cmp is usually for nonselective cmp purpose polishing both tungsten and dielectric material because its selectivity with oxide is not as high as alumina abrasive. Pdf slurry components in metal chemical mechanical. The machine is based on the popular kemet 15 lapping and polishing machine, but incorporates stainless steel elements in place of painted components for longer life, and contamination free polishing. Electrochemical behavior of aluminum during chemical. Chemical mechanical polishing composition and process ekc. Product safety assessment chemicalmechanical planarization.
The polishing pad 200 includes a composite pad body. A model of chemical mechanical modeling cmp is presented which quantitatively correlates the polishing rate with the slurry concentrations of both chemicals and abrasives. Controlled chemical mechanical polishing of polysilicon and. The abrasives in the polishing slurry were separated by using a centrifuge process and were mixed with deionized di water to create a chemical less polishing slurry figure 1. The physicochemical properties of slurry, such as particle size and distribution, surface chemistry, dispersion stability, and rheological behavior, are determined by the complex interaction between its components, which has significant influence on the chemical mechanical planarization cmp performances such as material removal rate, high planarity, uniformity, and defect. Facile production of mesoporous wo3rgo hybrids for highperformance supercapacitor electrodes. Controlled chemical mechanical polishing of polysilicon and silicon dioxide for singleelectron device vishwanath joshi,a alexei o.
In chemical mechanical polishingcmp, what role does the slurry chemical play. As a pioneer in chemical mechanical planarization cmp slurries, cabot microelectronics commercialized our original semisperse products in the 1980s for 250nm applications. Every element in stainless steel is located according to its own valence bond potential, forming a suitable metallic lattice structure. With continuous improvement of some of these slurries, enhanced versions are still in use and key to our customer solutions today, such as our flagship semisperse w2000. The cmp slurry composition is an important factor because additives in the slurry generally improve the polishing performance. In chemical mechanical polishingcmp, what role does the.
Analysis of slurry flow in chemical mechanical polishing by krzysztof d. Chemical mechanical polishing composition and process. Kopanski bachelor of science in mechanical and aerospace engineering cornell university, 2003 submitted to the department of. A w plug is formed without etching holes keyholes during chemical mechanical polishing with mno2 abrasive slurry. Disclosed herein are slurry compositions for use in cmpchemical mechanical polishing process of metal wiring in manufacturing. After chemical polishing, the workpieces are to be cleaned in the running water and dried. The slurry was tailored later to reduce defects and surface nonplanarity introduced by the. Reexamining chemical mechanical polishing pattern effects.
Copper chemical mechanical polishing using a slurryfree. Slurry components in metal chemical mechanical planarization. Slurry composition for use in chemical mechanical polishing of metal. Although the application of the slurry was an advance in the semiconductor technology, the slurry composition remained unchanged from the composition used in lens polishing. Chemical mechanical polishing of polymeric materials for. It can be thought of as a hybrid of chemical etching and free. Zantye university of south florida follow this and additional works at. The chemical elements of the cmp slurry react with the polished wafer surface and form a chemicallymodified top layer with properties different. Pdf chemical mechanical planarization cmp is a wet polishing technique. Processing, reliability and integration issues in chemical mechanical planarization parshuram b. Chemical mechanical planarization cabot microelectronics. Meat slurry, a mixture of finely ground meat and water, centrifugally dewatered and used as food. Mainly, the addition of certain organic acids was used in the cmp slurries, as for example picolinic acid.
Wo1998023408a1 a composition and slurry useful for metal cmp. The effects of applied pressure and polishing velocity are derived by considering the chemical reaction as well as the mechanical bearandshear processes. It is advisable to carry out chemical passivation of polished products. Chemical mechanical planarization of electronic materials. Chemicalmechanical planarization of semiconductor materials pp 215249 cite. Theory and experiment for several decades, chemical mechanical polishing cmp has been the most widely used planarization method in. A sufficient amount of a selectively oxidizing and reducing compound is provided in the composition to produce a differential removal of a metal and a dielectric material. The goal of the 1st phase cmp is to remove copper layer with high efficiency.
Chemical mechanical polishing cabot microelectronics. University, we developed a chemicalmechanical polishing cmp technique for removing the subsurface polishing damage prior to epitaxial growth of the singlecrystal sic films. Cmp uses three major components, a polisher, a pad and a slurry. Processing, reliability and integration issues in chemical. A slurry composition for chemical mechanical polishing cmp of a phasechange memory device is provided. Chemical mechanical polishing cmp is a process that, during the past 20 years, has achieved a high level of importance in various industrial sectors, particularly in microelectronics. This phase stops at the surface of the barrier layer. A sufficient amount of a selectively oxidizing and reducing compound is provided in the composition to produce a differential removal. However, it is limited to find the optimum conditions for the slurry by only experimental approaches. Chemical mechanical polishing cmp mechanisms of thermal. Effect of slurry composition on the chemical mechanical. The transformation in electronic devices that has occurred in the past few decades has relied greatly on the efficiency and effectiveness of planarization using slurry polishing.
The slurry residues in pores and grooves of polishing pad were also clearly removed by the hightemperature conditioning process, which aided the slurry to attack the oxide surface. An abrasive substance used in chemical mechanical polishing. Influence of chemical and mechanical polishing on water. Development of dishingless slurry for polysilicon chemicalmechanical polishing process to cite this article. Methods and compositions for electrochemicalmechanical polishing ecmp of silicon chip interconnect materials, such as copper, are provided. Four types of slurry were tested on cmp of the polymers under the same process conditions. Formula for polishing and buffing compounds for stainless. The present invention provides a slurry composition for chemical mechanical polishing comprising spinel particles having the formula aoxz 2 o 3 wherein a is at least one divalent cation, z is at least one trivalent cation, and 0. Hubbardhalls chemical polishing products burnish, smooth and brighten cleaning up the burrs, oxides, and contaminants that linger during manufacturing. Electrochemical analysis of the slurry composition for. A study of the chemical mechanical polishing cmp of thin copper films using fixedabrasive pads is presented. Snider department of electrical engineering, university of notre dame, notre dame, indiana 46556. Cmp chemical mechanical polishing studies show that.
The polishing pad 200 includes a composite pad body 202. The reasons were the need to planarize what was then advanced nextgeneration ic devices in a manner more reproducible and reliable than existing technology allowed. In this study, chemical mechanical polishing cmp of pc and pmma substrates was investigated. Read characterization of slurries used for chemical. Part of the springer series in materials science book series ssmaterials. A composition for chemical mechanical polishing includes a slurry. A novel approach of chemical mechanical polishing using. Chemical mechanical planarization cmp slurries selection. A novel approach of chemical mechanical polishing cmp is developed for mercury cadmium telluride hgcdte or mct semiconductors. Chemical mechanical polishing cmp has traditionally been considered an enabling technology. A slurry composition for chemical mechanical polishing, including 0. Tungsten film chemical mechanical polishing using mno 2 slurry. From a simple experiment, the mechanical portion and the chemical portion in the mrr can be explained.
Chemicalmechanical polishing cmp is often associated with chemicalmechanical planarization which is a polishing process assisted by chemical reactions to remove surface materials. The major question at present is whether mechanical or chemical effects are dominant. The effect of slurry composition and wafer flatness on a material removal rate mrr and resulting surface roughness which are evaluation parameters to determine the cmp characteristics of the onaxis 6hsic substrate were systematically investigated. A sufficient amount of a selectively oxidizing and reducing compound is provided in the composition to produce a differential removal of a.
Pdf chemical mechanical polishing slurry for amorphous. The composition of cmp slurry wastewaters is described, along with the principal physical and chemical. Analysis of slurry flow in chemicalmechanical polishing by krzysztof d. Formula for polishing and buffing compounds for stainless steel. The process combines the chemical acidic or basic effect of the slurry, which contains microabrasives with the mechanical effect provided by polishing to reduce the topography on the wafer or. The smaller the electronic components the more sophisticated the cmp process. An abrasive composition is provided based on the following.
Chemical mechanical polishing composition download pdf. The polishing pad 200 may be used in polishing stations, such as the polishing station 100, for polishing substrates by chemical mechanical polishing. We know that cmp is used for planarization of interconnects in ic fabrication and surface micromachining in mems. Chemical mechanical polishing how is chemical mechanical. The present invention provides a chemical mechanical planarization cmp polishing composition that polishes metal layers at a good removal rate and that provides good planarization of. The effect of slurry composition and flatness on subsurface. Chemical mechanical polishing planarization cmp slurries are abrasive materials, also. Chemical mechanical planarization slurry distribution system. The concept of chemical mechanical planarization cmp was. Mechanics, mechanisms and modeling of the chemical mechanical polishing process kyungyoon noh, jiunyu lai, nannaji saka, and junghoon chun abstract the chemical mechanical polishing cmp. Chemical mechanical polishing or planarization is a process of smoothing surfaces with the combination of chemical and mechanical forces.
Chemical mechanical planarization solutions chemical mechanical planarization cmp is a polishing process, which utilizes a chemical slurry formulation and mechanical polishing process to remove unwanted conductive or dielectric materials on the silicon wafer, achieving a nearperfect flat and smooth surface upon which layers of integrated circuitry are built. Chemical mechanical polishing, cabot microelectronics cmp. Chemicalmechanical impact of nanoparticles and ph effect. Chemical mechanical polishing cmp has attracted much attention recently because of its importance as a nanoscale finishing process for high valueadded large components that are used in the. Us6251150b1 slurry composition and method of chemical. With mno2 slurry, no key holes were formed even after overpolishing by an additional 0. The cmp process combines the chemical acidic or basic effect of the slurry, which contains microabrasives with the mechanical effect provided by polishing to reduce topography on the wafer surface. Nsfsrc engineering research center for environmentally benign semiconductor manufacturing philipossian 3.
Chemical mechanical planarization pt01003jt 4 a 2phase process is adopted in our inlaid copper pattern wafer polishing, which means changing slurry and working conditions during the copper removal process. Snider department of electrical engineering, university of notre dame. Study on slurry of chemical mechanical polishing 304. Effect of slurry composition on the chemical mechanical polishing of. Nanocrystalline diamond ncd thin films grown by chemical vapour deposition. Us20060118760a1 slurry composition and methods for. The theory of oxide polishing is not well understood, however, it is generally accepted that the alkaline chemistry hydrolyzes the oxide surface and subsurface thus weakening the sio 2 bond structure 1. Manure slurry, a mixture of animal waste, organic matter, and sometimes water often known simply as slurry in agricultural use, used as fertilizer after ageing in a slurry pit. It can be thought of as a hybrid of chemical etching and free abrasive polishing. This process uses a tool with a rotating wafer carrier single or multihead and a polishing pad placed on a rotating platen. Chemical polishing products for all substrates laser b.
Stainless steel will become one of the substrate materials used in flexible display. Mechanical polishing was performed in a bench vise using a rotating soft brush with pumice slurry followed by a rotating felt cone with chalk. Chemical mechanical polishing cmp is a finishing process that is used to prepare substrates for electronic devices. Global chemical polishing slurry market insights, forecast.
This process is poorly understood and in need of optimisation. Chemical mechanical planarization pt01003jt 4 a 2phase process is adopted in our inlaid copper pattern wafer polishing, which means changing slurry and working conditions during the copper. Chemical mechanical polishing planarization cmp is a critical step in semiconductor manufacturing. Analysis of slurry flow in chemicalmechanical polishing. Us patent for cmp pad construction with composite material. Chemical processes in glass polishing pdf free download. Controlled chemical mechanical polishing of polysilicon.
The polishing intensity at round type machines can be exceeded by combining mechanical and chemical exposure to polishing material. The abrasives in di water are dispersed using an agitator to. Kopanski submitted to the department of mechanical engineering on may 23, 2005 in partial fulfillment of the requirements for the degree of master of science in mechanical engineering abstract chemical mechanical polishing cmp is one of the enabling processes used in. The mechanochemical mechanism is generally accepted. Nanomaterials nm of silica sio 2, cerium ceo 2, and alumina al 2 o 3 are used in liquid slurries by a number of industrial applications, including chemical mechanical polishing planarization cmp processes used multiple times during production of computer chips. Chip surface topography after chemical mechanical polishing cmp process is determined by both process conditions and layout geometric characteristics. A chemical mechanical polishing slurry composition, comprising a polishing agent, an aminebased polishing activator, and a roughness adjusting agent, wherein the aminebased polishing activator is a tertiary or quaternary amine, and the roughness adjusting agent is a disaccharide. The mechanical energy imparted to the abrasive slurry particle through pressure.
Physical and chemical properties of industrial slurry explosives. Electrochemical behavior of aluminum during chemical mechanical polishing in phosphoric acid base slurry hongshi kuo and wenta tsai department of materials science and engineering, national. A chemical mechanical planarization cmp slurry comprising at least one abrasive particles at least one oxidizer, and at least one carrier. Also disclosed is a chemical mechanical polishing composition comprising an oxidizing agent and. The composition of the polishing solution is optimized by investigating the impact of both. The customer goal is to have flat, smooth, polished wafers. Slurry components in metal chemical mechanical planarization cmp process. The slurry composition comprises deionized water and iron or an iron compound. The new process was faster than the previous silica based polishing method and resulted in a mirrorlike surface blake and mendel, 1970. Ep3153558a1 chemical mechanical polishing composition.
Cmp compositions optionally contain surfactant to help wet surface. After machining, polishing, grinding processes, the elements located on the. Chemical mechanical planarization cmp slurries are liquid dispersions containing active chemicals and microabrasive grains used for chemical mechanical planarization. The composite pad body 202 includes one or more hard features 204 and one or more elastic features 206. The theory of oxide polishing is not well understood, however, it is generally accepted that the alkaline chemistry hydrolyzes the oxide surface. Control of nanomaterials used in chemical mechanical. In this paper, the influence of the ferric chloride and the oxalic acid on the material removal rate mrr and surface roughness had been studied in the chemical mechanical polishing cmp 304 stainless steel. Chemical mechanical planarization cmp chemical mechanical planarization cmp is a critical production step during microcircuit manufacturing. Sep 12, 2000 a composition for chemical mechanical polishing includes a slurry. A nanofilm model based on the pad roughness is used to explain the.
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